Moreover, the reactivity of trans-2-butene is compared to that of the other two isomers, 1-butene and isobutene, and these comparisons are discussed. Butene-1; Ethylethylene «alpha»-Butene «alpha»-Butylene; Sources. It has been validated using the IDT data measured here in addition to a large variety of literature data: jet-stirred reactor (JSR) speciation data, premixed flame speciation data, flow reactor speciation data and laminar flame speed data.
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Combustion is a reaction.
Moreover, liquefied petroleum gas (LPG) produced during oil refining contains significant amount of olefins, particularly propene and butenes, with gasoline fuel containing butenes, pentenes and hexenes in various amounts.
ScienceDirect ® is a registered trademark of Elsevier B.V.The oxidation of 2-butene: A high pressure ignition delay, kinetic modeling study and reactivity comparison with isobutene and 1-butene© 2016 The Combustion Institute.
A reaction doesn't have a formula; it is described by an equation. C4H8 + 6O2 ---> 4CO2 + 4H2O Following is the equation for the combustion of butene or butylene (C4H8). η: Dynamic viscosity (Pa×s). A comprehensive chemical kinetic mechanism has simultaneously been developed to describe the combustion of trans-2-butene.
NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data) Published by Elsevier Inc. All rights reserved.ScienceDirect ® is a registered trademark of Elsevier B.V. This is the first IDT data of trans-2-butene taken at engine relevant conditions, and the combination of HPST and RCM results greatly expands the range of data available for the oxidation of trans-2-butene to higher pressures (10–50 atm), lower temperatures (670–1350 K) and a wide range of equivalence ratios (0.5–2.0). C p,gas: Ideal gas heat capacity (J/mol×K).
C p,liquid: Liquid phase heat capacity (J/mol×K). alkanes) or alcohols present in conventional or reformulated fuels. In this study, a series of novel ignition delay time (IDT) experiments of trans-2-butene were performed in a high-pressure shock tube (HPST) and in a rapid compression machine (RCM) under conditions of relevance to practical combustors.
Alkenes are important intermediates formed by the combustion of larger hydrocarbons, e.g., alkanes and alcohols.
Δ f G°: Standard Gibbs free energy of formation (kJ/mol). Joback Method; NIST Webbook; Crippen Method; Δ c H° gas: Standard gas enthalpy of combustion (kJ/mol).
Important reactions are highlighted via flux and sensitivity analyses and help explain the differences in reactivity among the butene isomers.We use cookies to help provide and enhance our service and tailor content and ads. Butenes are intermediates ubiquitously formed by decomposition and oxidation of larger hydrocarbons (e.g.
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